Enhancement of CO2Affinity in a Polymer of Intrinsic Microporosity by Amine Modification
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چکیده
منابع مشابه
Enhancement of CO2 Affinity in a Polymer of Intrinsic Microporosity by Amine Modification
Nitrile groups in the polymer of intrinsic microporosity PIM-1 were reduced to primary amines using borane complexes. In adsorption experiments, the novel amine-PIM-1 showed higher CO2 uptake and higher CO2/N2 sorption selectivity than the parent polymer, with very evident dual-mode sorption behavior. In gas permeation with six light gases, the individual contributions of solubility and diffusi...
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ژورنال
عنوان ژورنال: Macromolecules
سال: 2014
ISSN: 0024-9297,1520-5835
DOI: 10.1021/ma401869p